Effect of Sm:Co ratio in SmCo nanocomposites on the structural, morphological and magnetic properties

Article Type : Research Article

Kavita Kumari1*, Naveen Yadav2, Mohit K. Sharma2, Sujata Kumari3, Pratibha Sharma3, Sameer Saharan4, Sarita Khaturia5, P. A. Alvi6, Bon-Heun Koo2* and Shalendra Kumar7*

Volume 5, Issue 1, Page 3-6, Year 2026, DOI :10.17571/appsletts.2026.01002

Abstract :

    This work reports the synthesis of SmCo based magnetic nanocomposites (MNCs) with varying Sm:Co ratio, prepared using chemical route technique followed by post synthesis heat treatment at 900 °C. The prepared samples were characterized using high resolution field emission scanning electron microscopy (HRFESEM), Energy Dispersive X-ray spectroscopy (EDS), X-ray Diffraction (XRD) and dc-magnetization to analyze the effect of Sm:Co ratio on the morphological, structural and magnetic properties of the MNCs. The HRFESEM images revealed the irregular shape morphology in a size range of 62 – 92 nm. The EDS maps and spectra confirmed the existence of Sm, Co and Oxygen in the samples. The XRD analysis revealed the presence of metallic cobalt, SmCo5 and Sm2O3 with varying phase fractions. The highest magnetization of 125.8 emu/g has been obtained for Sm:Co::1:1 corresponding to a magnetic anisotropy value of 1.44 x 106 erg/cm3. Sample with highest Co (>60%) showed highest saturation magnetization which was reduced with decreasing Co content. Thus, the magnetization behavior is found to be dependent on the nature of phases and their phase fractions.


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